(i) Given below are the steps for extraction of copper from its ore. Write the reaction involved. (a) Roasting of copper (I) sulphide (b) Reduction of copper (I) oxide with copper (I) sulphide. (c) Electrolytic refining (ii) Draw a neat and well labelled diagram for electrolytic refining of copper
The extraction behavior of Cu(II) ions from a real sulfate liquor obtained from the heap leaching stage of a copper oxide ore was investigated using a chelating reagent, Chemorex CP-150 in kerosene. A comparative study was also carried out on the extraction capability of Cu(II) ions using other solvents including D2EHPA and Cyanex 272.Chemorex CP-150 …
Copper can be extracted from non-sulfide ores by a different process involving three separate stages: Reaction of the ore (over quite a long time and on a huge scale) with a dilute acid such as dilute sulfuric acid to produce a very dilute copper(II) …
Abstract This research investigates the extraction behavior of copper and zinc from the sulfate leachate of a porcelain stone tailings sample with Chemorex CP-150 and D2EHPA in detail. The findings demonstrated that Chemorex had greater ability and selectivity in the extraction of copper, while D2EHPA was better in the extraction of …
Extracting copper from copper oxide. Method. Place a small amount of copper oxide in a beaker. Add about 20cm 3 of dilute sulphuric acid. Warm the mixture over a burner, stirring until no more oxide will dissolve. Filter the mixture an collect the filtrate in a clean beaker. Stand an iron nail the solution for a few minutes.
Recycling metals from secondary materials and more complex ores has recently been attracting more attention, creating a need for more precise separation methods of different elements. This study proposed a sulfation-roasting method and designed thermodynamic conditions to selectively facilitate the formation of copper …
The effect of chloride ions on the copper extraction equilibria, the rate of extraction, copper/iron selectivity, and chloride extraction was studied for organic phases containing pure ketoxime (LIX 84-IC) and pure nonylaldoxime (LIX 860N-IC). In these systems, the used aqueous phase contained total chloride concentrations from 0 to 110 g/l.
One of the equations that is used to describe copper extraction is Cu2S+2Cu2O→6Cu+So2. This equation illustrates how copper can be extracted from its ore by combining it with oxygen and …
Synergistic extraction of copper(II) from sulfate medium with capric acid and tri-n-octylphosphine oxide in chloroform F. ADJEL and D. BARKAT* Department of Industrial Chemistry, Faculty of ...
The extraction of copper was increased with increase in O:A ratio and 99.9% copper was extracted at O:A ratio of 5:1. The proposed extraction mechanism was found to be ion-associative and the nature of the extracted complex is octahedral. Back extraction of copper could be achieved with and above 0.1 mol/L H2SO4.
The solvent extraction of copper from a sulfate-chloride solution containing seawater and/or sodium chloride was studied using the commercial extractants LIX 984N and Acorga M5910. The effect of ...
The authors determined the effect of nitrate, ferric nitrate, ferric chloride and ferric sulfate on copper extraction. A mixed chloride-nitrate system was favorable for extracting copper from ...
The effect of leaching time on the extraction of copper, cobalt, and iron was studied from 1 h to 5 h under the constant conditions of 25 °C temperature, 50 g/L initial H 2 SO 4, and 4:1 mL/g liquid-solid ratio [Figure 9(a)]. The extraction of cobalt and copper increased with the extension of time, whereas that of iron remained unchanged.
Rao, Devi, and Reddy (2000) have studied the extraction and recovery of copper from a solution containing 0.1 M each of copper and sodium sulfate using MOC 45 as the extractant. Increase in ...
Obtained experimental data were used to develop a method of copper(II) extraction from Zn-Cu sulfate solution composed of 40.9 g/L Zn(II) and 1.2 g/L Cu(II). A flowsheet was tested in laboratory-scale reactors and the conducted test confirmed the possibility to selective recover of Cu(II) over Zn(II), and the concentration of Cu(II).
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WEBExtracting Copper From Other Ores. Copper can be extracted from non-sulfide ores by a different process involving three separate stages: Reaction of the ore (over quite a long …
In this research, the effect of operating variables on the extraction rate of copper from sulfate solution with new extractant Cupromex-3302 in the Lewis cell was studied. The rate equation for the mentioned system was obtained by changing different parameters such as concentration of Cu(II), Cupromex-3302, and H + while keeping …
Direct extraction of copper from copper sulfide minerals using deep eutectic solvents. Search articles by author. Copper is predominantly recovered from sulfide ores by …
The paper presents results of extraction of copper (II) from ammonia leach solutions. The effect of a type of extractant, its concentration and type of diluent in organic phase on extraction ...
The solvent extraction of copper from a sulfate-chloride solution containing seawater and/or sodium chloride was studied using the commercial extractants LIX 984N and Acorga M5910. The effect of chloride on the copper extraction equilibria, the copper-iron selectivity, and the extraction of chloride by the organic phases was evaluated.The …
The effect of pH has been studied for the extraction of copper in the pH range of 0.94–2.65 from 0.92 g/L Cu solution in sulfate medium using 5% LIX 84 diluted in kerosene.The pH of the solution has been adjusted with the addition of 1 N sodium hydroxide solution.The results presented in Fig. 1 indicate increase in copper extraction …
There are two steps in the extraction of copper metal from chalcocite, a copper ore. In the first step, copper(I) sulfide and oxygen react to form copper(I) oxide and sulfur dioxide: 2 Cu_2S(s)+3 O_2 ... Copper sulfate is a hydrated crystal with the formula CuSO_4 cdot 5H_2O and a deep blue colour. When it's heated, the crystals crumble and ...
Effect of equilibrium pH Extraction of copper was studied from an aqueous sulphate solution containing 0.005 M copper and 0.1 M sodium sulphate using 10% Žvrv. MOC 45 within the initial pH range of 0.9–5.85, the corresponding equilibrium pH values being in the range of 0.87– 2.79.
The extraction of copper from sulfate leaching liquor was investigated using Acorga M5640 commercial extractant in kerosene diluent. The effects of important factors such as the extractant ...
They showed that addition of barium sulfide to a copper sulfide melt suppressed copper sulfide's electrical conductivity enough to extract a small amount of pure copper from the high-temperature …
Zinc is the third most common nonferrous metal after aluminum and copper, which has wide application in the areas of plating, coating and alloying [1–3].Currently, 80 %–85 % zinc is produced from zinc sulfide concentrates by the hydrometallurgical methods of roasting-acid leaching-purifying-electrowinning process or oxygen pressure acid …
The ore used for extraction is copper pyrites, which is crushed, concentrated and then heated in the presence of air. During heating the moisture gets expelled and the copper pyrites gets converted to ferrous sulfide and cuprous sulfide. ... In fact you get a brown precipitate of copper and a blue solution of copper(II) sulfate …
The extraction of copper from sulfate leaching liquor was investigated using Acorga M5640 commercial extractant in kerosene diluent. The effects of important …
Doubling efficiency. The new work doubles the efficiency for electrolytic extraction of copper reported in the first paper, which was 28 percent with an electrolyte where only barium sulfide added to the copper sulfide, to 59 percent in the second paper with both lanthanum sulfide and barium sulfide added to the copper sulfide.
The method used to extract copper from its ores depends on the nature of the ore. Sulfide ores such as chalcopyrite ( CuFeS2 C u F e S 2) are converted to copper by a different method from silicate, carbonate or sulfate ores. Chalcopyrite (also known as copper pyrites) and similar sulfide ores are the commonest ores of copper.
ABSTRACT The effect of chloride ions on the copper extraction equilibria, the rate of extraction, copper/iron selectivity, and chloride extraction was studied for organic phases containing pure ketoxime (LIX 84-IC) and pure nonylaldoxime (LIX 860N-IC). In these systems, the used aqueous phase contained total chloride concentrations …
The resulting "pregnant" leach solution of sulfuric acid and copper sulfate is collected in a small pool. The copper compound can now be seen at concentrations of between 60-70%. The second step is solvent extraction, in which two immiscible (un-mixing) liquids are stirred and allowed to separate, causing the cooper to move from one liquid ...